Double and Triple Bonds in VSEPR Theory
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Double and Triple Bonds in VSEPR Theory


Molecular geometry is determined by possible locations of an electron in a valence shell, not by how many how many pairs of valence electrons are present.

         To see how the model works for a molecule with double bonds, consider carbon dioxide, CO2. Carbon has four pairs of bonding electrons, there are only two places electrons can be found in this molecule (in each of the double bonds with oxygen). Repulsion between the electrons is least when the double bonds are on opposite sides of the carbon atom. This forms a linear molecule that has a 180° bond angle.
    
            For another example, consider the carbonate ion, CO32-.

 As with carbon dioxide, there are four pairs of valence electrons around the central carbon atom. Two pairs are in single bonds with oxygen atoms, while two pairs are part of a double bond with an oxygen atom. This means there are three locations for electrons. Repulsion between electrons is minimized when the oxygen atoms form an equilateral triangle around the carbon atom. Therefore, VSEPR theory predicts the carbonate ion will take a trigonal planar shape, with a 120° bond angle.




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